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Solid-State NMR by Paul Hodgkinson, Robin K. Harris, David C. Apperley

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CHAPTER 6

QUADRUPOLAR NUCLEI

6.1 INTRODUCTION

This chapter is intended to give the reader an understanding of the unique characteristics of the quadrupolar interaction, which come into play when it is significant in magnitude compared with the Zeeman interaction, giving second-order effects. The reader is also introduced to the special techniques that are frequently necessary to obtain good-quality, well-resolved spectra of quadrupolar nuclei.

As briefly mentioned in chapter 1, quadrupolar nuclides are distinguished by the fact that they have spin quantum numbers greater than missing image file. Their NMR properties are substantially different from those of spin ...

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