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Solid-State NMR by Paul Hodgkinson, Robin K. Harris, David C. Apperley

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CHAPTER 4

QUANTUM MECHANICS OF SOLID-STATE NMR

4.1 INTRODUCTION

The previous chapters have deliberately avoided delving deeply into the theory underlying solid-state NMR. Indeed many solid-state NMR experiments can be understood in terms of the vector model familiar from the solution state (and discussed in section 3.2), so that most experiments can be interpreted using straightforward qualitative pictures of the different NMR interactions and their effects on the spectrum. As the subject has progressed, however, the complexity of experiments and the associated theoretical background have considerably increased. This chapter aims to provide an introduction to the various theoretical tools used in solid-state NMR. The Further reading lists ...

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