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The organizational control policies (OCPs) can be attached to your root, OU, or AWS accounts. At this time, only one kind of OCP is supported: SCP.
Accounts can only belong to one OU or root.
Similarly, OUs can only belong to one OU or root.
It's best to avoid deploying resources in the master account because this account can't be controlled with SCPs. The master account should be treated as a management account for audit, control, and billing purposes only.

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